Ultrahigh energy density in dielectric nanocomposites by modulating nanofiller orientation and polymer crystallization behavior

Electrostatic capacitors are a key component in high-power pulse equipment, power transmission and transformation engineering, new energy vehicles, and 5G communication. Their capability for ultrafast charging-discharging and ultrahigh power density is pivotal for their performance. Nonetheless, their relatively low capacitance and energy density restrict their rapid development toward the lightweight, flexible, integrated trend in electrical and electronic equipment. Overcoming the energy density bottleneck for dielectrics has thus become a research hotspot that urgently needs attention.

Electric breakdown strength and permittivity, or polarization, are two key parameters for high energy density in the dielectric. One of the most common strategies involves incorporating various ceramic nanoparticles such as BaTiO₃, SrTiO₃, among others, into high-insulation polymer matrix to leverage their respective advantages. However, achieving a significant increase in permittivity often requires a high loading of nanoparticles, which tends to increases electrical conductivity, thereby compromising the breakdown strength.

In a study published in the KeAi journal Advanced Powder Materials, a team of researchers from Central South University in Changsha, China, proposed a novel facile strategy to realize collaborative enhancement of breakdown strength and electric polarization for dielectric.

“Our strategy allows us to simultaneously achieve construction of in-plane oriented BaTiO₃ nanowire fillers and crystallization modulation of polyvinylidene fluoride (PVDF) matrix in an in-situ uniaxial stretch process” explain the study’s senior and corresponding author Dou Zhang.

Compared with zero-dimensional nanoparticles, one-dimensional nanowires with high aspect ratios have high polarizability and large dipole moment in the longitudinal direction, rendering them more effective in improving the permittivity of composite at lower loading levels while maintaining electric field endurance.

The research proved that high-strain stress induced the ultrahigh polar β phase and enhanced Young’s modulus facilitating a concurrent increase in both electric displacement and breakdown strength of polymer matrix. Notably, finite element simulation results revealed the oriented distribution of nanowires favors reducing the contact probability of nanowire tips, thus alleviating electric field concentration and hindering the breakdown path.

“The newly designed stretched PVDF-based nanocomposite is capable of operating with a voltage endurance as high as 843.0 kV/mm and simultaneously delivering an energy density of 40.9 J/cm³. This is by far the best capacitive performance ever achieved in polymer dielectrics,” adds Zhang.

Contact author details: 

Hang Luo (hangluo@csu.edu.cn), Dou Zhang (dzhang@csu.edu.cn).

Powder Metallurgy Research Institute, State Key Laboratory of Powder Metallurgy, Central South University, Changsha, 410083, China

Funder: 

This work is supported by the National Natural Science Foundation of China (52172265 and 52002404), Excellent Youth Science Foundation of Hunan Province (2022JJ20067), Central South University Innovation-Driven Research Program (2023CXQD010) and the State Key Laboratory of Powder Metallurgy.

Conflict of interest: 

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

See the article: 

by Guo Ru, et al. Ultrahigh energy density in dielectric nanocomposites by modulating nanofiller orientation and polymer crystallization behavior. Advanced Powder Materials, Volume 3, Issue 5, 2024, pages 100212. https://doi.org/10.1016/j.apmate.2024.100212